Porous molecular Crystals

Porous molecular Crystals

Porous molecular crystals are built on molecules able to assembly with an inefficient packing. So their extrinsic porosity define low density architectures, designed with weak interactions. We synthesized frameworks able to reversibly switch their conformation thanks to external stimuli.

 

 

 

 

 

 

 

 

 

 

 

 

  • Bassanetti I., Negroni M., Bezuidenhout C., Canossa S., Mazzeo P., Comotti A., Bracco S., Marchiò L., Sozzani P., “Porous Molecular Materials Responsive to CO2, CH4 and Xe Stimuli”. Journal of Material Chemistry A, 2018, 6, 14231-14239.

 

  • Baroncini M., d’Agostino S., Bergamini G., Ceroni P., Comotti A., Sozzani P., Bassanetti I., Grepioni F., Hernandez T.M., Silvi S., Venturi M., Credi A.. “Photoinduced reversible switching of porosity in molecular crystal”, Nature Chemistry, 2015, 7(8), 634-640.

 

  • Maspero A., Giovenzana G.B.,  Masciocchi N., Palmisano G., Comotti A., Sozzani P., Bassanetti I., Nardo L. “MÖhlau’s anthradipyrazole revisited: a new look at an old molecular system.”, Cryst.Growth Des. , 2013, 13, 4948-4956.